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Russia launched dozens of drones and missiles at Kyiv in the early hours of Tuesday, killing at least 10 people and wounding dozens of others, as negotiations faltered between Kyiv and Moscow.
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President Volodymyr Zelensky described the latest overnight barrage as "one of the most horrific attacks" on Kyiv since the Kremlin launched its brutal invasion of Ukraine more than three years ago.
Zelensky said a total of 440 drones and 32 missiles were launched in the strikes nationwide and urged the international community not to "turn a blind eye".
"(Russian President Vladimir) Putin does this solely because he can afford to continue the war. He wants the war to go on," he said.
AFP journalists saw smoke billowing over the capital's skyline at dawn and a multiple-storey housing block gutted by the attack. Rescue workers were scrambling to find any survivors buried beneath the rubble.
"It was probably the most hellish night in my memory for our neighbourhood," 20-year-old student Alina Shtompel told AFP.
"It is indescribably painful that our people are going through this right now."
More than three years into its full-scale invasion of Ukraine, Moscow has stepped up attacks despite efforts by the United States to broker a ceasefire.
Talks have stalled. Moscow has rejected the "unconditional" truce demanded by Kyiv and its European allies, while Ukraine has dismissed Russia's demands as "ultimatums".
- Diplomatic 'facade' -
Zelensky had been hoping to speak with US leader Donald Trump on the sidelines of the G7 summit in Canada, but the US leader cut short his visit, amid the escalating conflict between Israel and Iran.
Russia hit some 27 sites in Kyiv overnight and some residents were left without electricity, officials said.
"Twelve people have died as a result of Russian strikes on Ukraine overnight. Ten of them were in Kyiv and two more were pulled from the rubble in Odesa," Interior Minister Igor Klymenko said, revising down an earlier toll.
"During search and rescue operations, body parts may be found that are initially recorded as separate fatalities. Final confirmation is provided by forensic experts after analysis in a mobile DNA laboratory," he said, explaining the revision.
The Russian defence ministry said it had carried out precision strikes on "military-industrial facilities in the Kyiv region," in a statement similar to those releases after major attacks.
Germany vowed in response to "increase the pressure" on Russia. The strike showed that "Russia is using diplomacy merely as a facade," the foreign ministry wrote on X.
"Putin doesn't want a solution, he wants capitulation."
- US citizen dead -
Dozens of residents took shelter in a metro station in central Kyiv, sleeping on mats, exchanging information on attack or reassuring pets, AFP journalists reported, while drones buzzed and explosions echoed out over the city.
"I was asleep. There was a loud bang. The window was smashed, and glass rained down on me," Sergii, another Kyiv resident, said.
Residential buildings, educational institutions and "critical infrastructure facilities" were all hit, Interior Minister Klymenko said.
Shelling on the frontline Sumy and Kherson regions later in the day killed two others, authorities said.
Zelensky's chief of staff, Andriy Yermak, said the new attacks showed Moscow was "continuing its war against civilians".
Tens of thousands of soldiers have been killed on both sides since Russia invaded Ukraine in February 2022, according to independent monitors and Western intelligence agencies.
Russian forces have been steadily advancing across the sprawling front line even since the inauguration of Trump brought about an uptick in US efforts to secure a halt in fighting.